APADAZ, HYSINGLA ER, NORCO, REPREXAIN, VICODIN, VICODIN ES, VICODIN HP, VICOPROFEN, ZOHYDRO ER. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Ionization Energy/Potential: data unavailable, National Oceanic and Atmospheric Administration. 313c indicates that although not listed by name and CAS number, this chemical is reportable under one or more of the EPCRA section 313 chemical categories. They react as acids to neutralize bases. Inorganic anions, based on halogens, sulfur, phosphorus, nitrogen, carbon and silicon can be flushed down the drain with lots of water. & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. Will lead to extremely dangerous and corrosive fumes, which will decompose, resulting iodine vapors, Corrosive to organisms and rocks; Iodides have little toxicity to wildlife, Diluted solutions will break down harmlessly; Very concentrated solutions may explode if contaminated, Deadly for microbial life, extremely toxic for small animals and aquatic life, Very toxic for animals at high concentrations; Occurs naturally, but at low concentrations, Mixed with a more flammable solvent and safely incinerated; Controlled oxidation with chromic acid, piranha solution, Fenton's reagent, Occurs naturally; toxic and possibly carcinogen in high doses, Mixed with a flammable solvent and incinerated; Diluted in water and poured down the drain, Burns at high temperatures, releasing carbon dioxide, water vapors, acrolein, Little environmental impact from the literature available, Reduction with Zn/HCl; Dilution followed by decomposition with ferrous or ferric salts; Addition of ketone or aldehyde then heated to decompose, Dilution followed by addition of ketone or aldehyde then heated to decompose; Reduction with Zn/HCl, Decomposes releasing HCl and nitrogen oxides, Dilution followed by decomposition with ferrous or ferric salts; Addition of ketone or aldehyde then heated to decompose; Reduction with Zn/HCl, Dilution followed by precipitation of perchlorate with potassium ions, filtration then neutralization of hydroxylamine via addition of ketone or aldehyde, then heated to decompose; Reduction with Zn/HCl, Decomposes releasing nitrogen oxides, nitrogen, HCl, water vapors; explodes at high temperature, Decomposes releasing sulfur and nitrogen oxides, Any reducing agent, such as sodium metabisulfite, bisulfite, sulfite, thiosulfate, Decomposes to chlorine, chloric acid, hydrogen chloride, Very toxic and corrosive to organisms, especially aquatic ones, Decomposes to phosphoric acid, phosphorous acid, phosphine, Harmful and corrosive to organisms, especially aquatic ones, Yields carbon oxides, water vapors, leaves ash behind, Low toxicity; silver and copper-based inks may be harmful, Neutralization with potassium, calcium bases, followed by reduction with a suitable reducing agent to iodide; thiosulfate added to remove any free iodine, Decomposes at high temperatures to iodine pentoxide which further decomposes above 300 C to iodine and oxygen, Toxic to wildlife, both animals and plants, Neutralization with a solution sodium thiosulfate, Decomposes above melting point, releasing iodine and oxygen above 300 C, Neutralization with a cooled diluted solution of sodium hydroxide and sodium thiosulfate, Decomposes above melting point, releasing ICl and chlorine, Destruction with aqueous sodium hydroxide, Melts and decomposes near boiling point, releasing iodine, hydrogen iodine fumes, Dangerous to wildlife, especially if ingested; small animals are harmed easily, Gives off hydrogen chloride fumes in air and or moisture, Not always required; Ammonium hydroxide, carbonate/bicarbonate, Breaks down to iron(III) oxide and gives off sulfur dioxide and trioxide fumes, Safe, used in agriculture as iron supplement; May cause algal bloom if released in water bodies, Results in iron(III) oxide in the presence of air, Calcium hydroxide (slaked lime), followed by dilution, Gives off nitrogen oxide fumes, leaving behind iron(III) oxide, Harmful to environment in large and concentrated amounts; Diluted iron nitrate is a good source of iron and nitrogen for plants, Safe, sometimes used in agriculture as iron supplement; May cause algal bloom if released in water bodies, Breaks down into iron(III) oxide and gives off sulfur oxides, Incineration; oxidation with peroxide; both done outside, Decomposes, releasing copious amounts of iron oxide fumes, Flammable, gives off carbon dioxide and water vapor, Photolysis; Hydrolysis with cold sodium hydroxide solution, Neutralization with sodium hydroxide, followed by incineration, Neutralization with any acid; incineration; oxidation with Fenton's reagent, Flammable, burns to release carbon dioxide, water vapors and nitrogen; nitrogen dioxide may also be released, Toxic to all wildlife and especially aquatic life, Controlled oxidation with Fenton's reagent, Occurs naturally; toxic to microorganisms and other plants, Burns in the presence of air, to give off carbon dioxide and water vapors, Dangerous for wildlife and aquatic environment, Immersion underwater to prevent self-ignition, followed by adding a flocculating or a thickening agent to trap the phosphorus inside; resulting mass should be incinerated in a special incinerator, Pyrophoric, releases toxic sulfur dioxide and phosphorus pentoxide fumes, Pyrophoric, toxic and corrosive to the environment, Alkali carbonate or hydroxide; Lead precipitate should be taken to disposal facilities, Results in lead oxides; Yields carbon oxides, water vapors, Extremely toxic to all life, due to the good solubility of lead acetate, Nitrous acid, ammonium acetate, sodium dichromate, Decomposes to lead/lead(II) oxide releasing nitrogen gas and may explode during decomposition, Breaks down to its component oxides at high temperatures, Precipitation with a sulfide, carbonate or oxalate; wastes are to be taken to hazardous waste disposal centers, Breaks down in to lead oxide and releases nitrogen dioxide fumes, Extremely toxic to wildlife due to its good solubility in water, Decomposes around 500-1000 C in air to yield sulfur and lead oxides and lead metal fumes, Occurs naturally; Extremely toxic to the environment and all life, Precipitate with an excess of carbonate, oxalate or a sulfide; waste is to be taken to hazardous waste disposal centers, Results in lead oxide and acetic acid, carbon dioxide, water vapor, Corrosive and very toxic to all organisms, Incineration; oxidation; not always required, Results in carbon dioxide, water vapor, soot, Neutralization with an alkali or carbonate solution; recycling of lithium ions, Corrosive to organisms, will increase the aluminium concentration in soil or water, Neutralization with an alkali or carbonate solution; Slow addition in a large volume of water or alcohol;Recycling of lithium ions, Corrosive to organisms, will increase the boron concentration in soil or water, Hydrated form will give some oxychloride salt, Increases the chloride concentration in soil as well as lithium, Neutralization with a concentrated alkali or carbonate solution, alcohols, long chain alcohols are preferred; best performed in an open area, Any acid, carbon dioxide, sulfur dioxide; recycling is a good choice, Breaks down to lithium oxide and water vapor, Lithium has little effect to plant life, but will affect the nervous system of animals when ingested in excess, Any reducing agent, such as sodium metabisulfite, bisulfite, sulfite, thiosulfate; Hydrogen peroxide, Corrosive and harmful to organisms, especially aquatic ones, Precipitation; recycling; mixed with a combustible material and ignited, Breaks down to lithium oxide and nitrogen oxides, Nitrate is a source of nitrogen for plants; lithium has little effect to plant life, but will affect the nervous system of animals when ingested in excess, Oxidation with sodium percarbonate, oxygen, ozone to nitrate; Thermal decomposition followed by conversion to lithium carbonate or sulfate, Decomposes to form lithium oxide/hydroxide and releases nitrogen oxides fumes, Unlike nitrates, nitrites are poor source of nitrogen for plants; Lithium may be harmful for the central nervous system; Nitrites are toxic for most animals, Not required; can be poured down the drain, Burns releasing aluminium and magnesium oxides, Not useful; breaks down into magnesium oxide and carbon dioxide at high temperatures, May increase the magnesium and chloride content in the soil significantly, Not always required; any acid can be used, though a weak one is more economical, Decomposes at 350 C to magnesium oxide and releases water vapors, Raises the soil pH; source of magnesium for plants, Not required; an aqueous carbonate solution, like potassium carbonate can be used if necessary, Decomposes above 330 C to give off oxygen and nitrogen oxides, Good source of nitrogen and magnesium for plants (fertilizer); May cause algal bloom in water bodies, Will dehydrate when heated; Gives off sulfur oxides at very high temperature, Maybe be source of food for some organisms, Aqueous solutions or suspensions of base, carbonate, bicarbonate, Breaks down to manganese dioxide and gives off ozone; may explode, Burns organic material on contact, even wet organic material, Precipitated to managnese dioxide; Taken to waste disposal facilities; Dumped in trash, Melts; Releases carbon dioxide and water vapor at high temperatures, Cannot be digested by most organisms, but has no dangerous effects on wildlife, Cooled aqueous solution of diluted sodium hydroxide, added in excess, Safe, biodegradable; Occurs naturally in various plants, like peppermint, Decomposes over 580 C to yield sulfur oxides and mercury vapors, Conversion to cinnabar; Taken to hazardous waste disposal centers, Explodes, giving off carbon oxides, nitrogen gas and hazardous mercury vapors, Decomposes, releasing nitrogen dioxide, oxygen, mercury(II) oxide, mercury vapors, Decomposes over 500 C to yield mercury vapors, Taken to hazardous waste disposal centers; Conversion to cinnabar, Decomposes over 450 C to yield sulfur oxides and mercury vapors. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. It is used in making rayon, as a wood preservative, and as an analytical reagent. WebContact a licensed professional waste disposal service to dispose of this material.Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Offer surplus and non-recyclable solutions to a licensed disposal company.It is the responsibility of the waste All forms are soluble in water. WebZinc Sulfate, Reagent Grade, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Environmentally Hazardous Substance,solid, n.o.s. Do not treat the written disposal guidelines as absolute. Corrosion Irritation: Dermal: 10196-18-6 Skin - Rabbit Result : Severe skin irritation - 24 h Ocular: 10196-18-6 WebAcidic salts, such as ZINC SULFATE, are generally soluble in water. Many methods described in literature involve slowly bubbling the organic compound with a carrier gas in the Fenton solution, as this increases oxidation and limits splashing. This compound is insoluble in water and acids, showing little reactivity. Chemicals marked as "Oh yes!" Another simple solution is to reduce the ions back to the metal. Safe, biodegradable; Occurs naturally in various plants, like eucalyptus, peppermint, etc. Breaks down rapidly in the environment due to air and microorganisms, yielding sulfides and sulfates. As such, this method is generally considered a last resort in disposal, and it's mostly used for cleaning rather than disposal. Zinc sulfate is also obtained as a hexahydrate, ZnSO4.6H2O, and as a heptahydrate ZnSO4.7H2O. WebSoak up with inert absorbent material and dispose of as hazardous waste. (USCG, 1999). While this can sometimes be time consuming, it can often be more environmentally and economically friendly than discarding the waste in one manner or another is. Hocking, p. 216, http://www.drugfuture.com/chemdata/cuprous-sulfite.html, http://www.inchem.org/documents/sids/sids/115775.pdf, http://pubs.acs.org/doi/abs/10.1021/es7029703?journalCode=esthag, Safe disposal/handling of lead in a domestic setting, http://www.sciencemadness.org/smwiki/index.php?title=Proper_disposal_of_chemicals&oldid=14787, GNU Free Documentation License 1.3 or later, Oxidation with Fenton's reagent; Concentrated solution of sodium hydroxide, Safe detonation in remote area; Strong dilution in organic solvent followed by safe incineration; Hydrolysis with cold sodium hydroxide solution, Toxic to organisms; nitrate source for plants, Oxidation with an oxidizing solution, such as chromic acid, piranha solution, Fenton's reagent, Incineration (no peroxides); Oxidation with Fenton's reagent; Chlorination in water with chlorine or hypochlorous acid; If peroxides are present, addition of excess ferrous sulfate, sodium bisulfite or metabisulfite to neutralize the peroxides, followed by incineration; If the bottle has peroxides on the cap, do not open it, instead safely detonate it in a remote or special area, Incineration produces carbon dioxide and water vapor. WebAdd sodium bicarbonate solution. 5 National Oceanic and Atmospheric Administration. For each gram of barium salt, add 15 mL of 10% sodium sulfate solution. However, because only small amounts of compound gets neutralized at a time, this process takes a while. These you can pour down in your garden. Since the biggest hazard comes from the volatile and soluble heavy metal compounds, it's best to convert them into insoluble compounds, which are less toxic. In general, your designated place for pouring chemicals into the soil should be far from any gardens, horticulture or any other agricultural objects. After neutralization, you're left with a solution containing the salt of the neutralized acid. Decomposes at high temperatures to yield carbon oxides, water vapors, soot, VOCs, etc. Boils and breaks down to bromine, hydrogen bromide and phosphorous acids in the presence of air/moisture, Suspension of calcium hydroxide, sodium thiosulfate, cooled; PCl, Sodium thiosulfate solution/suspension; PI, Very toxic and corrosive to organisms and rocks, Suspension of calcium hydroxide, sodium thiosulfate, cooled; POBr, Suspension of calcium hydroxide, sodium thiosulfate, cooled; POCl, Oxidation with oxidizing solutions, such as chromic acid, Fenton's reagent, piranha solution, Hydrolysis with aqueous sodium hydroxide; oxidation with Fenton's reagent; Containers with dry picric acid should be taken by professionals and safely detonated in a remote location, Gives off carbon dioxide, water vapors, soot, VOCs, Strongly diluted with a flammable solvent and safely incinerated, Gives off carbon dioxide, water vapors, may explode if impurities present, Not required; Can simply be dumped in trash, Generates toxic fluorine, hydrogen fluoride, fluorocarbons and carbon oxide vapors, Resistant to most corrosive chemicals, cannot be digested by wildlife. Anhydrous zinc sulfate is a colorless crystalline solid. NaOH; Strong dilution; Oxidation with Fenton's reagent, Generates carbon oxides, water vapor, soot, sulfur oxides and HCl fumes, Incineration; Sodium pyrosulfite; L-cysteine, Generates carbon oxides and water vapors; some will evaporate when heated, Dilution in a more flammable solvent, followed by incineration; Oxidation with Fenton's reagent, Gives off carbon monoxide, dioxide, ammonia, acetonitrile, hydrogen cyanide, Addition to water followed by heating, yielding acetic acid and ammonium chloride, Anhydrous conditions yields ammonium chloride and acetonitrile; In presence of water acetic acid and ammonium chloride are formed, Flammable (high concentrations), no dangerous combustion products, Safe, biodegradable; avoid dumping large amounts, acidifies soil, Flammable, no dangerous combustion products, Biodegradable; avoid dumping large amounts, acidifies soil, Oxidation/incineration, reducing, photolysis, Biodegradable, though not advised for large amounts, Fenton's reagent; Aqueous solution of excess sodium hydroxide, All treatments give some hydrogen cyanide fumes, Toxic to all life due to its cyanide/nitrile group; does not quickly break down in environment, Mixed with a more flammable solvent and incinerated, Generates smoke, carbon dioxide and water vapors, Relative safe, biodegradable; Occurs naturally in small amounts, Burn products include hydrogen chloride which is corrosive, Extremely toxic and corrosive to organisms and environment, Gives off carbon dioxide and water vapors, Addition of a base, which causes polymerization, Burns in the presence of oxygen releasing carbon oxides, water, and various other organic products, Burning, dumping in ground; Desorption by heating it to high temperature and reuse, Unless it adsorbed dangerous volatile compounds or heavy metals, it can be used as a fertilizer (powdered form); Less effective as beads or pellets, Safe, biodegradable; nourishment for many organisms, Diluted with a flammable solvent, like ethanol or acetone and burned; Epoxidation and hydrolysis to glycerol, Loses magnetism when heated and melts at high temperatures, Nickel and cobalt are harmful for the environment, Generates smoke, carbon dioxide and water vapor, Treatment with water, precipitation with a base, No effect; Water solutions however will give off hydrogen chloride vapors, Treatment with water, precipitation with a base; recycling of iodine, No effect; Water solutions however will give off hydrogen iodide and iodine vapors, Incineration outside; Treatment with water, recovery of isopropanol and aluminium oxide/hydroxide or incineration of isopropanol, Melts and decomposes to give various ketones and isopropanol which may ignite; leaves behind alumina residue, Increases level of aluminium from soil, corrosive and harmful to organisms, Pyrolysis; Aqueous ammonia or alkaline hydroxide solution, Not always required, can be dumped in trash, Increases level of aluminium in soil, toxic to animals in large quantities, Burns in air, releasing fumes of phosphorus pentoxide and aluminium oxide, as well as traces of phosphine if any moisture is present, Releases phosphine gas on contact with water, which is deadly to organisms, Releases sulfur oxides at high temperature, Dilute it first; neutralization with a base first is recommended, Increases the aluminium concentration in soil and water, lowers pH, Releases hydrogen sulfide on contact with water, which is toxic to organisms, Burns, may detonate in the presence of metallic impurities, like copper, brass, While ammonium nitrate is a good nitrogen source for plants, TNT is very harmful for wildlife, Not required, can be discarded in any way, Pyrolysis gives nitrogen and carbon oxides, Not required, can be dumped in ground; Pyrolysis done outside, Pyrolysis gives nitrogen, water and carbon/nitrogen oxides, Little is known about its environmental impact, Not required, can be dumped in ground; Careful and controlled pyrolysis, Pyrolysis gives nitrogen, water and carbon/nitrogen oxides; may explode at high temperatures, Safe, nitrogen source for plants; Guanidine derivates occur in guano, Burns, may detonate in the presence of metallic impurities, like copper, While ammonium nitrate is a good nitrogen source for plants, the aluminium, TNT and other impurities present are harmful for wildlife, At high concentrations may generate nitrogen oxides, Not possible (gaseous), safe to pour (as solution), Not possible (gaseous), safe to pour (as solution); Good nitrogen source for plants, Slowly volatilizes and explodes at 400 C releasing nitrogen, hydrogen and ammonia gasses, Decomposes on heating releasing carbon dioxide, ammonia fumes and water vapors, Neutralize it with ammonia; can then poured down the drain, Decomposes to release sulfur oxides and ammonia, Yes, though recommended to neutralize first, Acidic, but once neutralized good nitrogen and sulfur source for plants, While it can be diluted and poured down the drain, it's recommended to neutralize it first; hydrogen peroxide and ammonia can be used to safely neutralize it, Decomposes to release sulfur dioxide and ammonia, Oxidation of aqueous ammonium bisulfite to bisulfate can reduce the amount of dissolved oxygen from water bodies and will lower water pH, Decomposes on heating releasing nitrogen, water, oxygen and hydrogen chloride, sometimes explosively, Decomposes on heating releasing ammonia and hydrogen chloride, Safe, good fertilizer (nitrogen source); May prove unsuitable to chloride sensitive plants, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid, at acidic pH, Decomposes, the famous volcano reaction, releasing nitrogen gas, water vapors, fine particulates of unburnt ammonium chromate, leaving behind Cr(III) oxide, Cr(VI) ions are carcinogenic and very toxic to organisms, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid at acidic pH, Decomposes, the famous volcano reaction, releasing nitrogen gas, water vapors, fine particulates of unburnt ammonium dichromate, leaving behind Cr(III) oxide, Not required; Slaked lime can be used to precipitate calcium phosphate, Safe, good fertilizer (nitrogen and phosphorus source), Decomposes on heating to release nitrogen, water and oxygen; may explode if heated too high, While it may be a good fertilizer, its environmental effects are unknown, Decomposes in several steps, releasing ammonia, water, cyanogen, ferric oxide, in air, Low toxicity, environmental effects unknown, Alkali hydroxide, carbonate, sulfate; heating in the presence of a base, Decomposes on heating to release ammonia, carbon monoxide, hydrogen cyanide and water, Alkali hydroxide, carbonate, sulfate; Dilution, poured down the drain, Decomposes on heating to release ammonia, water, leaving behind MoO, Diluted cooled hydrogen peroxide solution, Harmful to organisms, especially aquatic ones, Safe, good fertilizer (nitrogen, iron and sulfur source); May cause algal bloom in water bodies however, Safe, good fertilizer (nitrogen source); May cause algal bloom in water bodies however, Alkali hydroxides; strong dilution followed by heating; will slowly decompose even at room temperature, so you may leave it in a safe area and let it decompose, Decomposes or detonates, releasing nitrogen and water vapors, Decomposes quickly in environment, especially at low pH, Alkali hydroxide, carbonate, sulfate; pyrolysis in the presence of a base, Decomposes on heating to release ammonia, carbon monoxide, oximide, hydrogen cyanide and water vapors, May pose a threat to wildlife in large amounts; Occurs naturally in guano, Reduction with metallic iron under UV light in the absence of air; Heating perchlorate at 200 C with metallic iron for several hours, Decomposes to release nitrogen, water vapors, oxygen and hydrogen chloride, Dissolution in water, followed by reduction with sulfur dioxide or sodium sulfite, thiosulfate or metabisulfite, Detonates above 60-110 C, releasing nitrogen, water vapors and a smoke of manganese dioxide, Strong oxidizer and explosive, hazardous for wildlife, Pyrolysis, hydrolysis, various reducing agents, Decomposes at 120 C releasing sulfur and nitrogen oxides, oxygen and ammonia, Not required; Strong dilution is sufficient, Decomposes on heating to release ammonia, sulfur dioxide, sulfuric acid vapors, Considered to be environmentally friendly due to its degradation to non-harmful residues, Not required; Calcium hydroxide can be used to precipitate calcium sulfate, Safe, good fertilizer (nitrogen and sulfur source); slightly lowers the soil pH, Decomposes releasing hydrogen sulfide and ammonia, Extremely toxic for wildlife; Dangerous for the environment (DSD), Not required, simply pour down the drain; Bleach or hydrogen peroxide can be used if desired, Oxidation of aqueous ammonium sulfite to sulfate can reduce the amount of dissolved oxygen from water bodies; otherwise, safe, used as fertilizer, Precipitation with sodium hydroxide to less sodium fluorides, Emits very toxic fumes of hydrogen fluoride, nitrogen oxides and ammonia, Dilute then pour down the drain; Bleach or hydrogen peroxide can be used if desired, Decomposes to release sulfur dioxide, ammonia, water vapors, May be harmful for aquatic life; safe, used as fertilizer, While ammonium nitrate is a good nitrogen source for plants, the fuel oil (FO) from its composition is harmful for wildlife, Gives off carbon oxides, soot, nitrogen and or nitrogen oxides and water vapor, Dilution with a solvent, followed by incineration; Oxidation with an oxidizing solution, like Fenton's reagent, Gives off carbon oxides, soot and water vapor, While ammonium nitrate is a good nitrogen source for plants, nitromethane and methanol may be harmful for wildlife, Sublimes and decomposes, releasing carbon oxides, water vapors, soot, anilline, Mixed with a more flammable solvent and safely incinerated; Controlled oxidation with Fenton's reagent. 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Insoluble in water and acids, showing little reactivity decomposes at high to! Acids, showing little reactivity contain moderate concentrations of hydrogen ions and have pH 's of less than 7.0 rapidly... Making rayon, as a heptahydrate ZnSO4.7H2O, you 're left with a solution containing the salt the... The class is a CERCLA hazardous substance indicates that no RQ is to... Soot, VOCs, etc, add 15 mL of 10 % sodium sulfate solution salt of the acid! Is a CERCLA hazardous substance showing little reactivity than disposal of 10 % sodium sulfate solution simple. And as a heptahydrate ZnSO4.7H2O the environment due to air and microorganisms, yielding sulfides and sulfates as. Also obtained as a hexahydrate, ZnSO4.6H2O, and as a heptahydrate ZnSO4.7H2O little reactivity however, only... Such, this process takes a while in water and acids, showing little reactivity it 's mostly for...
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